Influence of the Chemical Structure of Soft Segment on the Properties of Polyurethane Acrylates
نویسنده
چکیده
Ultraviolet and heat-curable polyurethane acrylate prepolymers were synthesized from 4,4’-diphenyl methane diisocyanate, polyethylene adipate diol, polyhexamethylene carbonate diol, polycaprolactone diol and 1,6hexamethylene diamine , acrylic acid. Effects of nature of the soft segments on the physical properties were investigated. It was found that the thermal stability increased from polycarbonate diol to polyester diol. Tensile modulus and strength decreased for polyurethane acrylate based poly (ethylene adipate) diol. DSC scans show that all of the model polymers exhibit thermal transitions including a glass transition below – 35oC. These soft elastic segment structures, in addition to the physical and chemical cross-linked nature of hard segment, provide enough crosslink sites to have elastomeric behaviour.
منابع مشابه
Relationship between the Microstructure and Gas Transport Properties of Polyurethane/Polycaprolactone Blends
In this study, the relation between the permeation properties and structural characteristics of thermoplastic polyurethane based on polycaprolactone diol, TPU(PCL), and polycaprolactone (PCL) blends is investigated. for the purpsoes of this study, PU, PCL, and TPU/PCL blends containing 20 wt.% and 40 wt.% PCL were prepared via a solution blending method. The miscibility and good distribution of...
متن کاملبررسی خواص مکانیکی و حرارتی کوپلی یورتان های بر پایه GAP-PPG با نسبت های متفاوت
For improving the mechanical and thermal properties of polyurethanes based on glycidyl azide polymer (GAP), a series of polyurethane elastomers with two soft segments were prepared from hexamethylene diisocyanate (HDI) / (GAP) / (PPG) /TMP and isophorone diisocyanate (IPDI) / GAP/ PPG/ TMP formulation. The weight ratio of soft segments GAP/PPG in polyurethane samples is changed as following ord...
متن کاملبررسی اثر زنجیر افزاینده‌ها در تغییر خواص فیزیکی، مکانیکی و انرژی‌زایی بایندرهای پلی‌یورتانی گرمانرم
Polyurethanes are the most well known polymers used to make a binder in high energy material. Polyurethanes aregenerally synthesized by the reaction of diisocyanates and polyols and chain extender.These polymers are often two-phase morphology.Chain extenders are small diols or diamines that are inserted to the hard segment of of polyurethane chain. chemical structure of chain extender, the ...
متن کاملInvestigating the effects of chemical modification of clay nanoparticles on thermal degradation and mechanical properties of TPU/nanoclay composites
Thermoplastic polyurethane (TPU)/clay nanocomposites were prepared via a melt-compounding method using ester type TPU and two different modified organoclays (Cloisite 30B and Cloisite 15A) in different contents. The Effects of the chemical structure and content of the nanoclays on the thermal degradation and mechanical properties of TPU were also investigated. The effect of structural modificat...
متن کاملبررسی اثر عاملیت هیدروکسیل بر خواص مکانیکی الاستومرهای پلی یورتانی بر پایه پلی بو تا دی ان با گروه هیدروکسیل انتهایی (HTPB)
Composite propellants are often identified by the type of polymeric binder used. The most commonly used polyol in recent time is the Hydroxyl Terminated Polybutadiene (HTPB). In order to evaluate the quality of three types of HTPB prepolymer, their polyurethanes elastomers were synthesized by one shot polymerization and structure-properties relationships of the prepared polyurethane have ...
متن کامل